Details
Manufacturer Supply Best Quality 4H,4'H-OCTAFLUOROBIPHENYL 3883-86-1 with Efficient Transportation
- Molecular Formula: C12H2F8
- Molecular Weight: 298.135
- Melting Point: 84-86 °C(lit.)
- Boiling Point: 222.4 °C at 760 mmHg
- Flash Point: 73.9 °C
- PSA： 0.00000
- Density: 1.582 g/cm3
- LogP: 4.46640
3883-86-1 Relevant articles
Hydrodefluorination of Fluoroarenes Using Hydrogen Transfer Catalysts with a Bifunctional Iridium/NH Moiety
Matsunami, Asuka,Kuwata, Shigeki,Kayaki, Yoshihito
, p. 5181 - 5185 (2016)
The hydrodefluorination of fluoroarenes ...
-
Contigiani,R.A. et al.
, p. 7 - 15 (1971)
-
Diazaphospholene-Catalyzed Hydrodefluorination of Polyfluoroarenes with Phenylsilane via Concerted Nucleophilic Aromatic Substitution
Zhang, Jingjing,Zhao, Xiao,Yang, Jin-Dong,Cheng, Jin-Pei
supporting information, p. 294 - 300 (2022/01/03)
The metal-free catalytic C-F bond activa...
Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers
Cornella, Josep,Katzenburg, Felix,Leutzsch, Markus,N?thling, Nils,Pang, Yue
supporting information, p. 12487 - 12493 (2021/08/30)
Herein, we report a hydrodefluorination ...
Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4
Schoch, Timothy D.,Mondal, Mukulesh,Weaver, Jimmie D.
supporting information, p. 1588 - 1593 (2021/03/03)
Presented is an economical means of remo...
Palladium-Catalyzed Homocoupling of Highly Fluorinated Arylboronates: Studies of the Influence of Strongly vs Weakly Coordinating Solvents on the Reductive Elimination Process
Budiman, Yudha P.,Friedrich, Alexandra,Jayaraman, Arumugam,Kerner, Florian,Marder, Todd B.,Radius, Udo
supporting information, p. 6036 - 6050 (2020/04/27)
C-C reductive elimination from [PdL2(C6F...
3883-86-1 Process route
-
-
1073339-11-3
4,4,5,5-tetramethyl-2-(2,3,5,6-tetrafluorophenyl)-1,3,2-dioxaborolane
-
-
3883-86-1
2,2',3,3',5,5',6,6'-octafluoro-1,1'-biphenyl
| Conditions | Yield |
|---|---|
|
With
palladium diacetate; silver(l) oxide;
In
toluene;
at 75 ℃;
for 5h;
Sealed tube;
|
97%
|
-
-
434-90-2
decafluorobiphenyl
-
-
3883-86-1
2,2',3,3',5,5',6,6'-octafluoro-1,1'-biphenyl
| Conditions | Yield |
|---|---|
|
With
water; triethylphosphine;
In
1,4-dioxane;
at 120 ℃;
for 4h;
Schlenk technique;
Inert atmosphere;
Glovebox;
|
100%
|
|
With
H2SiEt2; tetrabutylammonium triphenyldifluorosilicate;
In
tetrahydrofuran; benzene-d6;
at 40 ℃;
for 40h;
Inert atmosphere;
Sealed tube;
|
97%
|
|
With
H2SiEt2; C16H19BiN2O2;
In
tetrahydrofuran;
at 60 ℃;
for 20h;
Inert atmosphere;
Sealed tube;
|
95%
|
|
With
phenylsilane; 2-H-1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaphosphole;
In
acetonitrile;
at 100 ℃;
for 3h;
Inert atmosphere;
Schlenk technique;
|
92%
|
|
With
sodium tetrahydroborate;
In
dimethyl sulfoxide;
at 45 ℃;
|
84%
|
|
With
tetrakis(trimethylphosphine)cobalt(0); sodium formate;
In
dimethyl sulfoxide;
for 8h;
Catalytic behavior;
Inert atmosphere;
|
80.5%
|
|
Multi-step reaction
with
2
steps
1: N2
H4
*H2
O / aq. ethanol
2: CuSO4
, aq. potassium sodium tartrate, NaOH
With
sodium hydroxide; Rochelle's salt; hydrazine hydrate; copper(II) sulfate;
In
ethanol;
|
|
|
With
tris[2-phenylpyridinato-C2,N]iridium(III); N-ethyl-N,N-diisopropylamine;
In
acetonitrile;
at 0 ℃;
for 45h;
Inert atmosphere;
Irradiation;
|
3883-86-1 Upstream products
-
10386-84-2
4,4'-dibromo-2,3,5,6,2',3',5',6'-octafluoro-1,1'-biphenyl
-
5243-24-3
3-iodo-1,2,4,5-tetrafluorobenzene
-
92-52-4
biphenyl
-
2200-68-2
perfluoro-(4,4'-byphenyldiyl)-dihydrazine
3883-86-1 Downstream products
-
142781-24-6
{Ni(PCH3 (C6 H5 )2)2}2(C6 F4 C6 F4 )(C6 F4 C6 F4 H)2
-
142781-21-3
Ni(PCH3 (C6 H5 )2)2(C6 F4 C6 F4 H)Br
-
142781-23-5
{Ni(PCH3 (C6 H5 )2)2}2(C6 F4 C6 F4 )Br2
-
27127-02-2
(C6 H5 )3SnSC6 F4 C6 F4 SSn(C6 H5 )3
