Details
Reputable factory supply 4'-(Trifluoromethoxy)acetophenone 85013-98-5 in stock with high standard
- Molecular Formula: C9H7F3O2
- Molecular Weight: 204.149
- Appearance/Colour: clear yellow liquid
- Vapor Pressure: 0.0311mmHg at 25°C
- Refractive Index: n20/D 1.455(lit.)
- Boiling Point: 215.4 °C at 760 mmHg
- Flash Point: 87.8 °C
- PSA: 26.30000
- Density: 1.265 g/cm3
- LogP: 2.78780
4'-(Trifluoromethoxy)acetophenone(Cas 85013-98-5) Usage
|
General Description |
4′-(Trifluoromethoxy)acetophenone is an organic building block. It is also referred as p-(trifluoromethoxy)acetophenone. |
InChI:InChI=1/C8H3Cl2F3O/c9-6-4(7(10)14)2-1-3-5(6)8(11,12)13/h1-3H
85013-98-5 Relevant articles
Radical C?H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide
Dix, Stefan,Golz, Paul,Schmid, Jonas R.,Riedel, Sebastian,Hopkinson, Matthew N.
supporting information, p. 11554 - 11558 (2021/07/09)
Trifluoromethoxylated (hetero)arenes are...
Green Synthesis of Leaning Tower[6]arene-Mediated Gold Nanoparticles for Label-Free Detection
Zhang, Hao,Wang, Xin,Huang, Kun-Tao,Liang, Feng,Yang, Ying-Wei
supporting information, p. 4677 - 4682 (2021/06/28)
Here a facile synthesis strategy toward ...
Bipyridinium and Phenanthrolinium Dications for Metal-Free Hydrodefluorination: Distinctive Carbon-Based Reactivity
Burton, Katherine I.,Elser, Iris,Waked, Alexander E.,Wagener, Tobias,Andrews, Ryan J.,Glorius, Frank,Stephan, Douglas W.
supporting information, p. 11730 - 11737 (2021/07/16)
The development of novel Lewis acids der...
Covalent Organic Frameworks Enabling Site Isolation of Viologen-Derived Electron-Transfer Mediators for Stable Photocatalytic Hydrogen Evolution
Mi, Zhen,Zhou, Ting,Weng, Weijun,Unruangsri, Junjuda,Hu, Ke,Yang, Wuli,Wang, Changchun,Zhang, Kai A. I.,Guo, Jia
supporting information, p. 9642 - 9649 (2021/03/16)
Electron transfer is the rate-limiting s...
85013-98-5 Process route
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-
456-55-3
1-trifluoromethoxybenzene
-
-
75-36-5
acetyl chloride
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-
34888-05-6
(trichloromethoxy)benzene
-
-
85013-98-5
1-[4-(trifluoromethoxy)phenyl]ethan-1-one
| Conditions | Yield |
|---|---|
|
With
aluminium trichloride;
In
tetrachloromethane;
for 2h;
Further Variations:;
Solvents;
Product distribution;
|
20%
80% |
-
-
366-18-7
[2,2]bipyridinyl
-
-
106-93-4
ethylene dibromide
-
-
85-00-7
diquat dibromide
| Conditions | Yield |
|---|---|
|
for 12h;
Reflux;
|
93%
|
|
In
nitrobenzene;
at 210 ℃;
for 3h;
Temperature;
Time;
|
92.7%
|
|
In
acetone;
at 80 ℃;
for 20h;
|
92%
|
|
at 130 ℃;
for 16h;
|
89%
|
|
for 3.5h;
Reflux;
|
28%
|
|
With
nitrobenzene;
|
|
|
|
|
|
at 130 ℃;
for 17h;
|
|
|
In
nitrobenzene;
Reflux;
|
|
|
In
acetonitrile;
at 100 ℃;
for 48h;
|
|
|
In
acetone;
at 150 ℃;
for 10h;
Sealed tube;
|
|
|
In
acetonitrile;
for 4h;
Reflux;
|
85013-98-5 Upstream products
-
456-55-3
1-trifluoromethoxybenzene
-
75-36-5
acetyl chloride
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79619-25-3
1-[4-(trifluoromethoxy)phenyl]pentan-1-one
-
99-93-4
4-Hydroxyacetophenone
85013-98-5 Downstream products
-
286959-65-7
ethyl 2-cyano-3-(4-trifluoromethoxyphenyl)-2-butenoate
-
1209050-26-9
1-[4-(trifluoromethoxy)phenyl]ethylamine
-
639784-61-5
ETHYL-3-(4-TRIFLUOROMETHOXYPHENYL) PYRAZOLE-5-CARBOXYLATE
-
474707-71-6
3-(4-trifluoromethoxyphenyl)-1H-pyrazole
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