4'-(Trifluoromethoxy)acetophenone

  • CAS:85013-98-5
  • purity:99%
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Details

Reputable factory supply 4'-(Trifluoromethoxy)acetophenone 85013-98-5 in stock with high standard

  • Molecular Formula: C9H7F3O2
  • Molecular Weight: 204.149
  • Appearance/Colour: clear yellow liquid 
  • Vapor Pressure: 0.0311mmHg at 25°C 
  • Refractive Index: n20/D 1.455(lit.)  
  • Boiling Point: 215.4 °C at 760 mmHg 
  • Flash Point: 87.8 °C 
  • PSA: 26.30000 
  • Density: 1.265 g/cm3 
  • LogP: 2.78780 

4'-(Trifluoromethoxy)acetophenone(Cas 85013-98-5) Usage

General Description

4′-(Trifluoromethoxy)acetophenone is an organic building block. It is also referred as p-(trifluoromethoxy)acetophenone.

InChI:InChI=1/C8H3Cl2F3O/c9-6-4(7(10)14)2-1-3-5(6)8(11,12)13/h1-3H

85013-98-5 Relevant articles

Radical C?H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide

Dix, Stefan,Golz, Paul,Schmid, Jonas R.,Riedel, Sebastian,Hopkinson, Matthew N.

supporting information, p. 11554 - 11558 (2021/07/09)

Trifluoromethoxylated (hetero)arenes are...

Green Synthesis of Leaning Tower[6]arene-Mediated Gold Nanoparticles for Label-Free Detection

Zhang, Hao,Wang, Xin,Huang, Kun-Tao,Liang, Feng,Yang, Ying-Wei

supporting information, p. 4677 - 4682 (2021/06/28)

Here a facile synthesis strategy toward ...

Bipyridinium and Phenanthrolinium Dications for Metal-Free Hydrodefluorination: Distinctive Carbon-Based Reactivity

Burton, Katherine I.,Elser, Iris,Waked, Alexander E.,Wagener, Tobias,Andrews, Ryan J.,Glorius, Frank,Stephan, Douglas W.

supporting information, p. 11730 - 11737 (2021/07/16)

The development of novel Lewis acids der...

Covalent Organic Frameworks Enabling Site Isolation of Viologen-Derived Electron-Transfer Mediators for Stable Photocatalytic Hydrogen Evolution

Mi, Zhen,Zhou, Ting,Weng, Weijun,Unruangsri, Junjuda,Hu, Ke,Yang, Wuli,Wang, Changchun,Zhang, Kai A. I.,Guo, Jia

supporting information, p. 9642 - 9649 (2021/03/16)

Electron transfer is the rate-limiting s...

85013-98-5 Process route

1-trifluoromethoxybenzene
456-55-3

1-trifluoromethoxybenzene

acetyl chloride
75-36-5

acetyl chloride

(trichloromethoxy)benzene
34888-05-6

(trichloromethoxy)benzene

1-[4-(trifluoromethoxy)phenyl]ethan-1-one
85013-98-5

1-[4-(trifluoromethoxy)phenyl]ethan-1-one

Conditions
Conditions Yield
With aluminium trichloride; In tetrachloromethane; for 2h; Further Variations:; Solvents; Product distribution;
20%
80%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

ethylene dibromide
106-93-4

ethylene dibromide

diquat dibromide
85-00-7

diquat dibromide

Conditions
Conditions Yield
for 12h; Reflux;
93%
In nitrobenzene; at 210 ℃; for 3h; Temperature; Time;
92.7%
In acetone; at 80 ℃; for 20h;
92%
at 130 ℃; for 16h;
89%
for 3.5h; Reflux;
28%
With nitrobenzene;
at 130 ℃; for 17h;
In nitrobenzene; Reflux;
In acetonitrile; at 100 ℃; for 48h;
In acetone; at 150 ℃; for 10h; Sealed tube;
In acetonitrile; for 4h; Reflux;

85013-98-5 Upstream products

  • 456-55-3
    456-55-3

    1-trifluoromethoxybenzene

  • 75-36-5
    75-36-5

    acetyl chloride

  • 79619-25-3
    79619-25-3

    1-[4-(trifluoromethoxy)phenyl]pentan-1-one

  • 99-93-4
    99-93-4

    4-Hydroxyacetophenone

85013-98-5 Downstream products

  • 286959-65-7
    286959-65-7

    ethyl 2-cyano-3-(4-trifluoromethoxyphenyl)-2-butenoate

  • 1209050-26-9
    1209050-26-9

    1-[4-(trifluoromethoxy)phenyl]ethylamine

  • 639784-61-5
    639784-61-5

    ETHYL-3-(4-TRIFLUOROMETHOXYPHENYL) PYRAZOLE-5-CARBOXYLATE

  • 474707-71-6
    474707-71-6

    3-(4-trifluoromethoxyphenyl)-1H-pyrazole

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