Details
1-CHLORO-3-METHOXY-2-PROPANOL 4151-97-7 with purity >99% Low price in stock
- Molecular Formula:C4H9 Cl O2
- Molecular Weight:124.567
- Vapor Pressure:0.247mmHg at 25°C
- Refractive Index:1.4463
- Boiling Point:181.6°Cat760mmHg
- PKA:13.28±0.20(Predicted)
- Flash Point:63.6°C
- PSA：29.46000
- Density:1.13g/cm3
- LogP:0.23250
1-CHLORO-3-METHOXY-2-PROPANOL(Cas 4151-97-7) Usage
|
Synthesis Reference(s) |
The Journal of Organic Chemistry, 53, p. 275, 1988 DOI: 10.1021/jo00237a009Synthetic Communications, 24, p. 1959, 1994 DOI: 10.1080/00397919408010203 |
InChI:InChI=1/C4H9ClO2/c1-7-3-4(6)2-5/h4,6H,2-3H2,1H3
4151-97-7 Relevant articles
Cellulose sulfate: An efficient heterogeneous catalyst for the ring-opening of epoxides with alcohols and anilines
Chaudhary, Pooja,Deepa,Meena, Dhan Raj,Aalam, Mohd Jubair,Yadav, Geeta Devi,Singh, Surendra
supporting information, p. 1834 - 1846 (2021/05/10)
Cellulose sulfate was synthesized by est...
Rational design 2-hydroxypropylphosphonium salts as cancer cell mitochondria-targeted vectors: Synthesis, structure, and biological properties
Amerhanova, Syumbelya K.,Dimukhametov, Mudaris N.,Gubaidullin, Aidar T.,Islamov, Daut R.,Litvinov, Igor A.,Lyubina, Anna P.,Mironov, Vladimir F.,Nemtarev, Andrey V.,Pashirova, Tatiana N.,Titov, Eugenii A.,Tsepaeva, Olga V.,Voloshina, Alexandra D.
, (2021/11/01)
It has been shown for a wide range of ep...
MBA-cross-linked poly(N-vinyl-2-pyrrolidone)/ferric chloride macromolecular coordination complex as a novel and recyclable Lewis acid catalyst: Synthesis, characterization, and performance toward for regioselective ring-opening alcoholysis of epoxides
Rahmatpour, Ali,Zamani, Maryam
, (2021/09/30)
A novel macromolecular-metal coordinatio...
Selective synthesis of epichlorohydrin: Via liquid-phase allyl chloride epoxidation over a modified Ti-MWW zeolite in a continuous slurry bed reactor
Ding, Luoyi,Yin, Jinpeng,Tong, Wen,Peng, Rusi,Jiang, Jingang,Xu, Hao,Wu, Peng
, p. 331 - 342 (2021/01/11)
The epoxidation of allyl chloride (ALC) ...
4151-97-7 Process route
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-
107-05-1
3-chloroprop-1-ene
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-
4151-97-7
1-chloro-3-methoxypropan-2-ol
-
-
96-24-2
3-monochloro-1,2-propanediol
-
-
106-89-8,24969-06-0,13403-37-7
epichlorohydrin
| Conditions | Yield |
|---|---|
|
With
dihydrogen peroxide;
TS-1;
In
methanol; water; 1,2-dichloro-benzene;
at 25 - 40 ℃;
for 1h;
Product distribution / selectivity;
|
94% |
-
-
67-56-1
methanol
-
-
106-89-8,24969-06-0,13403-37-7
epichlorohydrin
-
-
4151-97-7
1-chloro-3-methoxypropan-2-ol
| Conditions | Yield |
|---|---|
|
With
Nafion NR50;
at 65 ℃;
for 2h;
Reagent/catalyst;
Inert atmosphere;
|
98.9% |
|
With
ammonium cerium(IV) nitrate;
at 65 ℃;
for 0.5h;
|
95% |
|
2,3-dicyano-5,6-dichloro-p-benzoquinone;
for 1h;
Heating;
|
94% |
|
With
tin(IV)tetraphenylporphyrinato trifluoromethanesulfonate;
for 1h;
Heating;
|
94% |
|
With
fiber supported Fe(III) complex catalyst (PANFDTA(at)Fe(III));
at 80 ℃;
for 2h;
regioselective reaction;
Green chemistry;
|
94% |
|
With
sodium perchlorate;
for 6h;
Ambient temperature;
electrolysis;
|
92% |
|
iron(III) trifluoroacetate;
at 65 ℃;
for 2h;
|
92% |
|
With
sulfuric acid; silica gel;
at 20 ℃;
for 2h;
|
92% |
|
With
ammonium cerium(IV) nitrate;
for 0.25h;
Heating;
|
91% |
|
With
silica gel; iron(III) chloride;
at 25 ℃;
for 3.5h;
|
91% |
|
With
cerium(IV) triflate;
at 65 ℃;
for 0.666667h;
|
90% |
|
aluminum oxide; molybdenum(VI) oxide;
at 20 ℃;
for 0.666667h;
|
90% |
|
With
N-methylpyrrolidine-2-one hydrotribromide;
at 20 ℃;
for 1.5h;
regioselective reaction;
Neat (no solvent);
|
89% |
|
With
bismuth(III) chloride;
for 1h;
Heating;
|
87% |
|
With
iodine; polyvinylpyrrolidone;
at 25 ℃;
for 5.5h;
|
86% |
|
With
trichloro(trifluoromethanesulfonato)titanium(IV);
for 1.5h;
Heating;
|
86% |
|
With
iron(III) perchlorate;
at 20 ℃;
for 5h;
|
86% |
|
With
(NH4)8[CeW10O36]*20H2O;
for 1h;
Heating;
|
86% |
|
With
iron(III);
for 1h;
Ambient temperature;
|
85% |
|
With
organotin phosphate;
for 5h;
Heating;
|
83% |
|
Sn-P Cat;
for 5h;
Heating;
|
83% |
|
With
tris
|
80% |
|
With
GaCl3 supported on cross-linked polyvinylpyrrolidone;
at 20 ℃;
for 4h;
regioselective reaction;
|
80% |
|
With
boron trifluoride diethyl etherate;
for 20h;
Heating;
|
77% |
|
With
cellulose sulfate;
at 0 - 25 ℃;
for 24h;
regioselective reaction;
Cooling with ice;
|
77% |
|
Montmorillonite K 10;
In
tetrachloromethane;
for 10h;
Heating;
|
73% |
|
With
boron trifluoride diethyl etherate;
for 15h;
Reflux;
|
67% |
|
With
iron(III) chloride;
at 65 ℃;
for 2.5h;
|
65% |
|
With
boron trifluoride diethyl etherate;
for 20h;
|
62% |
|
With
N-Bromosuccinimide;
at 20 ℃;
for 24h;
|
30% |
|
tin(IV) chloride;
Thermodynamic data;
Mechanism;
Kinetics;
other temperature, ΔH(activ.), ΔS(activ.);
|
|
|
With
sulfuric acid;
|
|
|
With
hydrogen fluoride;
|
|
|
With
sulfuric acid;
|
|
|
With
boron trifluoride;
|
|
|
With
sulfuric acid;
at 67 - 68 ℃;
for 12h;
|
|
|
tin(IV) chloride;
at 29.9 ℃;
|
|
|
With
cation-exchange resin (Dowex 50W-X8);
at 50 ℃;
for 15h;
|
|
|
With
tin(IV) chloride;
at 30 ℃;
Further Variations:;
Temperatures;
Kinetics;
Thermodynamic data;
Activation energy;
|
|
|
With
silica gel; iron(III) perchlorate;
at 20 ℃;
|
|
|
K5
|
94 % Chromat. |
|
With
zinc(II) chloride;
Heating;
|
|
|
at 60 - 75 ℃;
|
|
|
With
graphene oxide;
at 20 ℃;
for 24h;
regioselective reaction;
|
|
|
With
ferrocenium(III) tetrafluoroborate;
at 25 ℃;
for 20h;
|
99 %Chromat. |
|
With
Palladium supported on strontium hydroxyl fluoride;
at 27 ℃;
for 2h;
regioselective reaction;
|
89 %Chromat. |
|
With
graphitic carbon nitride nanosheets;
at 120 ℃;
for 5h;
|
99.4 %Chromat. |
|
at 180 ℃;
under 14710.2 Torr;
|
|
|
With
tin(IV) chloride;
|
|
|
With
Fe(III) ion immobilized on N,N′-methylenebisacrylamide cross-linked poly(N-vinyl-2-pyrrolidone) copolymer;
at 20 ℃;
for 0.5h;
Reagent/catalyst;
regioselective reaction;
Catalytic behavior;
|
91 %Chromat. |
4151-97-7 Upstream products
-
623-39-2
glycerol 1-monomethyl ether
-
67-56-1
methanol
-
106-89-8
epichlorohydrin
-
1072-61-3
4-chloromethyl-[1,3]dioxolane
4151-97-7 Downstream products
-
92737-67-2
1-methoxy-3-phenyl-2-propanol
-
13635-03-5
3-Hydroxy-4-methoxy-buttersaeure-mitril
-
93072-46-9
N-[2,2,2-Trichloro-1-(1-chloromethyl-2-methoxy-ethoxy)-ethyl]-benzenesulfonamide
-
86027-02-3
1-[2-(4-Bromo-phenylazo)-imidazol-1-yl]-3-methoxy-propan-2-ol
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